An activation product is a material that has been made radioactive by the process of neutron activation.

Process

Fission products and actinides produced by neutron absorption of nuclear fuel itself are normally referred to by those specific names, and activation product reserved for products of neutron capture by other materials, such as structural components of the nuclear reactor or nuclear bomb, the reactor coolant, control rods or other neutron poisons, or materials in the environment. In these cases their production is undesired and they need to be handled as radioactive waste. Some nuclides can be produced both as activation products or as fission products. For example molybdenum-99 which is an important nuclide in "molybdenum cows" used in medical diagnostics can be produced either by fissioning 235U or by neutron irradiation of 98Mo.

Practical uses

However, neutron activation (usually in a dedicated research reactor, but sometimes also in power reactors like the CANDUs at Bruce nuclear generating station) is also used deliberately to produce desired radioisotopes for uses in food irradiation, nuclear medicine and to sterilize equipment via gamma radiation emitted from isotopes such as Cobalt-60.

Activation products in a reactor's primary coolant loop are a main reason reactors use a chain of two or even three coolant loops linked by heat exchangers.

Fusion reactors will not produce radioactive waste from the fusion product nuclei themselves, which are normally just helium-4, but generate high neutron fluxes, so activation products are a particular concern.

List of activation products

Activation product radionuclides include:

Half-lives and decay branching fractions for activation products
NuclideHalf-lifeDecay modebranching fractionSourceNotes
3 1H12.312 ± 0.025 yβ−1.0LNHB
10 4Be( 1.51 ± 0.06 ) × 106 yβ−1.0ENSDF
14 6C( 5.7 ± 0.03 ) × 103 yβ−1.0LNHB
15 6C2.449 ± 0.005 sβ−1.0ENSDF
16 7N7.13 ± 0.02 sβ−1.0ENSDF
19 8O26.88 ± 0.05 sβ−1.0ENSDF
22 11Na950.57 ± 0.23 dEC0.1011 ± 0.0002aIAEA-CRP-XG[1]
β+0.8989 ± 0.0002a
24 11Na0.62329 ± 0.00006 dβ−1.0IAEA-CRP-XG
27 12Mg9.458 ± 0.012 mβ−1.0ENSDF
26 13Al( 7.17 ± 0.24 ) × 105 yEC0.1825 ± 0.0023bLNHB[2]
β+0.8175 ± 0.0023b
35 16S87.32 ± 0.16 dβ−1.0LNHB
36 17Cl( 0.01 ± 0.03 ) × 105 yEC0.019 ± 0.001LNHB
β−0.981 ± 0.001
39 18Ar269 ± 3 yβ−1.0ENSDF
41 18Ar109.61 ± 0.04 mβ−1.0ENSDF
40 19K( 4.563 ± 0.013 ) × 1011 dEC0.1086 ± 0.0013aIAEA-CRP-XG[1]
β−0.8914 ± 0.0013a
42 19K12.36 ± 0.012 hβ−1.0ENSDF
41 20Ca( 1.02 ± 0.07 ) × 105 yEC1.0ENSDF
45 20Ca162.61 ± 0.09 dβ−1.0ENSDF
47 21Sc3.3492 ± 0.0006 dβ−1.0ENSDF
48 21Sc43.67 ± 0.09 hβ−1.0ENSDF
51 24Cr27.7009 ± 0.002 dEC1.0IAEA-CRP-XG
54 25Mn312.29 ± 0.26 dEC1.0IAEA-CRP-XG
56 25Mn0.107449 ± 0.000019 dβ−1.0IAEA-CRP-XG
55 26Fe( 1.0027 ± 0.0023 ) × 103 dEC1.0IAEA-CRP-XG
59 26Fe44.494 ± 0.013 dβ−1.0IAEA-CRP-XG
57 27Co271.8 ± 0.05 dEC1.0IAEA-CRP-XG
58 27Co70.86 ± 0.06 dβ+0.15 ± 0.0020aIAEA-CRP-XG[1]
EC0.85 ± 0.0020a
60 27Co( 1.92523 ± 0.00027 ) × 103 dβ−1.0IAEA-CRP-XG
59 28Ni( 7.6 ± 0.5 ) × 104 yEC1.0ENSDF
63 28Ni98.7 ± 2.4 yβ−1.0LNHB
65 28Ni2.51719 ± 0.00026 hβ−1.0ENSDF
64 29Cu0.52929 ± 0.00018 dβ+0.179 ± 0.002aIAEA-CRP-XG[1]
β−0.39 ± 0.003a
EC0.431 ± 0.005a
66 29Cu5.12 ± 0.014 mβ−1.0ENSDF
65 30Zn243.86 ± 0.2 dβ+0.0142 ± 0.0001aIAEA-CRP-XG[1]
EC0.9858 ± 0.0001a
93m 41Nb( 5.73 ± 0.22 ) × 103 dIT1.0IAEA-CRP-XG
93 42Mo( 4.0 ± 0.8 ) × 103 yEC1.0ENSDF
99m 43Tc0.250281 ± 0.000022 dβ−0.000037 ± 0.000006aIAEA-CRP-XG[1]
IT0.999963 ± 0.000006a
110m 47Ag249.85 ± 0.1 dIT0.0136 ± 0.0008aIAEA-CRP-XG[1]
β−0.9864 ± 0.0008a
115m 49In4.486 ± 0.004 hβ−0.05 ± 0.008ENSDF
IT0.95 ± 0.008
126 53I12.93 ± 0.05 dβ−0.473 ± 0.006ENSDF
EC0.527 ± 0.006
175 72Hf70 ± 2 dEC1.0ENSDF
181 72Hf42.39 ± 0.06 dβ−1.0ENSDF
182 73Ta114.43 ± 0.04 dβ−1.0ENSDF
181 74W121.2 ± 0.2 dEC1.0ENSDF
185 74W75.1 ± 0.3 dβ−1.0ENSDF
187 74W23.72 ± 0.06 hβ−1.0ENSDF
198 79Au2.695 ± 0.0007 dβ−1.0IAEA-CRP-XG
197 80Hg64.14 ± 0.05 hEC1.0ENSDF
203 80Hg46.594 ± 0.012 dβ−1.0IAEA-CRP-XG
LNHBLaboratoire National Henri Becquerel, Recommended Data, 2021-02-13 at the Wayback Machine, 5 June 2008.
IAEA-CRP-XGM.-M. Bé, V.P. Chechev, R. Dersch, O.A.M. Helene, R.G. Helmer, M. Herman, S. Hlav ác, A. Marcinkowski, G.L. Molnár, A.L. Nichols, E. Schönfeld, V.R. Vanin, M.J. Woods, IAEA CRP "Update of X Ray and Gamma Ray Decay Data Standards for Detector Calibration and Other Applications", IAEA Scientific and Technical Information report STI/PUB/1287, May 2007, International Atomic Energy Agency, Vienna, Austria, ISBN 92-0-113606-4.
ENSDFEvaluated Nuclear Structure Data File, , 5 June 2008.

[1] Branching fractions from LNHB database.

[2] Branching fractions renormalised to sum to 1.0..

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