Calcium propanoate or calcium propionate is a chemical compound with the chemical formula Ca(C2H5COO)2. It is the calcium salt of propanoic acid.

Uses

Food additive

As a food additive, it is listed as E number 282 in the Codex Alimentarius. Calcium propionate is used as a preservative in a variety of products including bread, baked goods, processed meat, whey, and dairy products. It is only effective in foods with a pH of 5.5 or below (i.e., foods that are relatively more acidic).

In bakery products, it acts as a mold inhibitor, typically added at 0.1–0.4%. Calcium propionate and sodium propionate are effective against both Bacillus mesentericus (rope) and mold.

Agriculture

In agriculture, it is used to prevent milk fever in cows and as a feed supplement.

It can be used as a fungicide on fruit.

Industrial

It is of research interest in the production of belite cement clinkers and as a dual NOx/SOx reducing agent in coal furnaces.

Reactions

Thermal decomposition in an inert atmosphere follows a radical mechanism that yields 3-pentanone. In the presence of oxygen, an exothermic reaction occurs involving the formation of carbon dioxide, carbon monoxide, acetaldehyde, methane and water. This occurs at approximately 310 °C (590 °F; 583 K), while the radical pathway occurs near the melting point at 385 °C (725 °F; 658 K). Both pathways end in the formation of calcite.

Safety

In a 1973 study reported by the EPA, the waterborne administration of 180 ppm of calcium propionate was found to be slightly toxic to bluegill sunfish.

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