| | William Petty 2nd Earl of Shelburne | 27 March 1782 | 10 July 1782 | Whig | Rockingham II | George III (1760–1820) |
| | Thomas Townsend MP for Whitchurch | 10 July 1782 | 2 April 1783 | Whig | Shelburne (Whig–Tory) |
| | Frederick North Lord North MP for Banbury | 2 April 1783 | 19 December 1783 | Tory | Fox–North |
| | George Nugent-Temple-Grenville 3rd Earl Temple | 19 December 1783 | 23 December 1783 | Tory | Pitt I |
| | Thomas Townsend 1st Baron Sydney | 23 December 1783 | 5 June 1789 | Whig |
| | William Grenville 1st Baron Grenville MP for Buckinghamshire (1759–1834) | 5 June 1789 | 8 June 1791 | Tory |
| | Henry Dundas MP for Edinburgh | 8 June 1791 | 11 July 1794 | Tory |
| | William Cavendish-Bentinck 3rd Duke of Portland | 11 July 1794 | 30 July 1801 | Tory |
| Addington |
| | Thomas Pelham 4th Baron Pelham of Stanmer | 30 July 1801 | 17 August 1803 | Whig |
| | Charles Philip Yorke MP for Cambridgeshire | 17 August 1803 | 12 May 1804 | Tory |
| | Robert Jenkinson 2nd Baron Hawkesbury | 12 May 1804 | 5 February 1806 | Tory | Pitt II |
| | George Spencer 2nd Earl Spencer | 5 February 1806 | 25 March 1807 | Whig | All the Talents (Whig–Tory) |
| | Robert Jenkinson 2nd Earl of Liverpool | 25 March 1807 | 1 November 1809 | Tory | Portland II |
| | Richard Ryder MP for Tiverton | 1 November 1809 | 8 June 1812 | Tory | Perceval |
| | Henry Addington 1st Viscount Sidmouth | 11 June 1812 | 17 January 1822 | Tory | Liverpool |
| George IV (1820–1830) |
| | Robert Peel MP for Oxford University | 17 January 1822 | 10 April 1827 | Tory |
| | William Sturges Bourne MP for Ashburton | 30 April 1827 | 16 July 1827 | Tory | Canning (Canningite–Whig) |
| | | Henry Petty-Fitzmaurice 3rd Marquess of Lansdowne | 16 July 1827 | 22 January 1828 | Whig |
| Goderich |
| | Robert Peel MP for 3 constituencies respectively (1788–1850) | 26 January 1828 | 22 November 1830 | Tory | Wellington–Peel |
| William IV (1830–1837) |
| | William Lamb 2nd Viscount Melbourne | 22 November 1830 | 16 July 1834 | Whig | Grey |
| | John Ponsonby 1st Baron Duncannon | 19 July 1834 | 15 November 1834 | Whig | Melbourne I |
| | Arthur Wellesley 1st Duke of Wellington | 15 November 1834 | 15 December 1834 | Tory | Wellington Caretaker |
| | Henry Goulburn MP for Cambridge University | 15 December 1834 | 18 April 1835 | Conservative | Peel I |
| | Lord John Russell MP for Stroud | 18 April 1835 | 30 August 1839 | Whig | Melbourne II |
| Victoria (1837–1901) |
| | Constantine Phipps 1st Marquess of Normanby | 30 August 1839 | 30 August 1841 | Whig |
| | Sir James Graham 2nd Baronet MP for Dorchester | 6 September 1841 | 30 June 1846 | Conservative | Peel II |
| | Sir George Grey 2nd Baronet MP for Devonport → North Northumberland(1799–1882) | 8 July 1846 | 23 February 1852 | Whig | Russell I |
| | Spencer Horatio Walpole MP for Midhurst | 27 February 1852 | 19 December 1852 | Conservative | Who? Who? |
| | Henry John Temple 3rd Viscount Palmerston MP for Tiverton | 28 December 1852 | 6 February 1855 | Whig | Aberdeen (Peelite–Whig) |
| | Sir George Grey 2nd Baronet MP for Morpeth | 8 February 1855 | 26 February 1858 | Whig | Palmerston I |
| | Spencer Horatio Walpole MP for Cambridge University | 26 February 1858 | 3 March 1859 | Conservative | Derby–Disraeli II |
| | Thomas Henry Sutton Sotheron-Estcourt MP for North Wiltshire | 3 March 1859 | 18 June 1859 | Conservative |
| | George Cornewall Lewis MP for Radnor | 18 June 1859 | 25 July 1861 | Liberal | Palmerston II |
| | | Sir George Grey 2nd Baronet MP for Morpeth | 25 July 1861 | 28 June 1866 | Liberal |
| Russell II |
| | Spencer Horatio Walpole MP for Cambridge University | 6 July 1866 | 17 May 1867 | Conservative | Derby–Disraeli III |
| | Gathorne Gathorne-Hardy MP for Oxford University | 17 May 1867 | 3 December 1868 | Conservative |
| | Henry Bruce MP for Merthyr Tydfil → Renfrewshire(1815–1895) | 9 December 1868 | 9 August 1873 | Liberal | Gladstone I |
| | Robert Lowe MP for London University | 9 August 1873 | 20 February 1874 | Liberal |
| | R. A. Cross MP for South West Lancashire | 21 February 1874 | 23 April 1880 | Conservative | Disraeli II |
| | William Harcourt MP for Derby | 28 April 1880 | 23 June 1885 | Liberal | Gladstone II |
| | R. A. Cross MP for Newton | 24 June 1885 | 1 February 1886 | Conservative | Salisbury I |
| | Hugh Childers MP for Edinburgh South | 6 February 1886 | 25 July 1886 | Liberal | Gladstone III |
| | Henry Matthews MP for Birmingham East | 3 August 1886 | 15 August 1892 | Conservative | Salisbury II |
| | H. H. Asquith MP for East Fife | 18 August 1892 | 25 June 1895 | Liberal | Gladstone IV |
| Rosebery |
| | Matthew White Ridley MP for Blackpool | 29 June 1895 | 12 November 1900 | Conservative | Salisbury (III & IV) (Con.–Lib.U.) |
| | Charles Ritchie MP for Croydon | 12 November 1900 | 11 August 1902 | Conservative |
| Edward VII (1901–1910) |
| Balfour |
| | Aretas Akers-Douglas MP for St Augustine's | 11 August 1902 | 5 December 1905 | Conservative |
| | Herbert Gladstone MP for Leeds West | 11 December 1905 | 19 February 1910 | Liberal | Campbell-Bannerman |
| | Asquith (I–III) |
| | Winston Churchill MP for Dundee | 19 February 1910 | 24 October 1911 | Liberal |
| George V (1910–1936) |
| | Reginald McKenna MP for North Monmouthshire | 24 October 1911 | 27 May 1915 | Liberal |
| | John Simon MP for Walthamstow | 27 May 1915 | 12 January 1916 | Liberal | Asquith Coalition (Lib.–Con.–et al.) |
| | Herbert Samuel MP for Cleveland | 12 January 1916 | 7 December 1916 | Liberal |
| | George Cave 1st Viscount Cave MP for Kingston (1856–1928) | 11 December 1916 | 14 January 1919 | Conservative | Lloyd George (I & II) |
| | Edward Shortt MP for Newcastle upon Tyne West | 14 January 1919 | 23 October 1922 | National Liberal |
| | William Bridgeman MP for Oswestry | 25 October 1922 | 22 January 1924 | Conservative | Law |
| Baldwin I |
| | Arthur Henderson MP for Burnley (1863–1935) | 23 January 1924 | 4 November 1924 | Labour | MacDonald I |
| | William Joynson-Hicks MP for Twickenham | 7 November 1924 | 5 June 1929 | Conservative | Baldwin II |
| | John Robert Clynes MP for Manchester Platting | 8 June 1929 | 26 August 1931 | Labour | MacDonald II |
| | Herbert Samuel MP for Darwen | 26 August 1931 | 1 October 1932 | Liberal | National I (N.Lab.–Con.–et al.) |
| | National II |
| | Sir John Gilmour 2nd Baronet MP for Glasgow Pollok | 1 October 1932 | 7 June 1935 | Unionist |
| | | John Simon MP for Spen Valley | 7 June 1935 | 28 May 1937 | Liberal National | National III (Con.–N.Lab.–et al.) |
| Edward VIII (1936) |
| | George VI (1936–1952) |
| | Samuel Hoare MP for Chelsea | 28 May 1937 | 3 September 1939 | Conservative | National IV |
| | | John Anderson MP for Combined Scottish Universities | 4 September 1939 | 4 October 1940 | Independent (National) | Chamberlain War |
| | Churchill War (All parties) |
| | Herbert Morrison MP for Hackney South | 4 October 1940 | 23 May 1945 | Labour |
| | Donald Somervell MP for Crewe | 25 May 1945 | 26 July 1945 | Conservative | Churchill Caretaker (Con.–Lib.N.) |
| | James Chuter Ede MP for South Shields | 3 August 1945 | 26 October 1951 | Labour | Attlee (I & II) |
| | David Maxwell Fyfe MP for Liverpool West Derby | 27 October 1951 | 19 October 1954 | Conservative | Churchill III |
| Elizabeth II (1952–2022) |
| | | Gwilym Lloyd George MP for Newcastle upon Tyne North | 19 October 1954 | 14 January 1957 | National Liberal & Conservative |
| Eden |
| | Rab Butler MP for Saffron Walden | 14 January 1957 | 13 July 1962 | Conservative | Macmillan (I & II) |
| | | Henry Brooke MP for Hampstead | 14 July 1962 | 16 October 1964 | Conservative |
| Douglas-Home |
| | Frank Soskice MP for Newport | 18 October 1964 | 23 December 1965 | Labour | Wilson (I & II) |
| | Roy Jenkins MP for Birmingham Stechford | 23 December 1965 | 30 November 1967 | Labour |
| | James Callaghan MP for Cardiff South East | 30 November 1967 | 19 June 1970 | Labour |
| | Reginald Maudling MP for Barnet | 20 June 1970 | 18 July 1972 | Conservative | Heath |
| | Robert Carr MP for Carshalton | 18 July 1972 | 4 March 1974 | Conservative |
| | Roy Jenkins MP for Birmingham Stechford | 5 March 1974 | 10 September 1976 | Labour | Wilson (III & IV) |
| | Callaghan |
| | Merlyn Rees MP for Leeds South | 10 September 1976 | 4 May 1979 | Labour |
| | William Whitelaw MP for Penrith and The Border | 4 May 1979 | 11 June 1983 | Conservative | Thatcher I |
| | Leon Brittan MP for Richmond (Yorks) | 11 June 1983 | 2 September 1985 | Conservative | Thatcher II |
| | Douglas Hurd MP for Witney | 2 September 1985 | 26 October 1989 | Conservative |
| Thatcher III |
| | David Waddington MP for Ribble Valley | 26 October 1989 | 28 November 1990 | Conservative |
| | Kenneth Baker MP for Mole Valley | 28 November 1990 | 10 April 1992 | Conservative | Major I |
| | Kenneth Clarke MP for Rushcliffe | 10 April 1992 | 27 May 1993 | Conservative | Major II |
| | Michael Howard MP for Folkestone and Hythe | 27 May 1993 | 2 May 1997 | Conservative |
| | Jack Straw MP for Blackburn | 2 May 1997 | 8 June 2001 | Labour | Blair I |
| | David Blunkett MP for Sheffield Brightside | 8 June 2001 | 15 December 2004 | Labour | Blair II |
| | Charles Clarke MP for Norwich South | 15 December 2004 | 5 May 2006 | Labour |
| Blair III |
| | John Reid MP for Airdrie and Shotts | 5 May 2006 | 28 June 2007 | Labour |
| | Jacqui Smith MP for Redditch | 28 June 2007 | 5 June 2009 | Labour | Brown |
| | Alan Johnson MP for Hull West and Hessle | 5 June 2009 | 11 May 2010 | Labour |
| | Theresa May MP for Maidenhead Tenure | 12 May 2010 | 13 July 2016 | Conservative | Cameron–Clegg (Con.–L.D.) |
| Cameron II |
| | Amber Rudd MP for Hastings and Rye | 13 July 2016 | 29 April 2018 | Conservative | May I |
| | May II |
| | Sajid Javid MP for Bromsgrove | 30 April 2018 | 24 July 2019 | Conservative |
| | Priti Patel MP for Witham | 24 July 2019 | 6 September 2022 | Conservative | Johnson I |
| Johnson II |
| | Suella Braverman MP for Fareham | 6 September 2022 | 19 October 2022 | Conservative | Truss |
| Charles III (2022–present) |
| | Grant Shapps MP for Welwyn Hatfield | 19 October 2022 | 25 October 2022 | Conservative |
| | Suella Braverman MP for Fareham | 25 October 2022 | 13 November 2023 | Conservative | Sunak |
| | James Cleverly MP for Braintree | 13 November 2023 | 5 July 2024 | Conservative |
| | Yvette Cooper MP for Pontefract, Castleford and Knottingley | 5 July 2024 | 5 September 2025 | Labour | Starmer |
| | Shabana Mahmood MP for Birmingham Ladywood | 5 September 2025 | Incumbent | Labour |
| Burnham |