General structure of polychlorinated carbazoles

Polychlorinated carbazoles (PCCZ) are a group of chlorinated organic compounds. They are derivatives of carbazole and nitrogen analogues of polychlorinated dibenzofurans.

Polychlorinated carbazoles usually occur as a mixture of various isomers. This mixture can have a certain frequency pattern (congener pattern) from which conclusions can be drawn about the causes of formation.

PCCZs are not manufactured purposefully. They are formed under certain conditions as by-products of thermal processes. In environmental samples, mixed halogenated carbazoles are also found.

congeners
Chlorine atomsPCCZ isomers
1004
2016
3028
4038
5028
6016
7004
8001
Total135

Further reading

  • Juliane Kirst: Synthesis of polyhalogenated carbazoles and total synthesis of amaryllidaceae alkaloids pratosine and hippadine. Dissertation, Dresden, 2009. (in German) DNB-IDN
  • Victor Turoski (1997), (in German), CRC Press, p. 96, ISBN 9781575040660
  • Liu, Hongyan; Yi, Zhongsheng; Mo, Lingyun: In: Acta Chim. Sinica, 2009, 67(14), 1626–1634.